Selective adsorption of benzhydroxamic acid on fluorite rendering selective separation of fluorite/calcite

摘要

Graphical abstractDisplay OmittedHighlights•Benzhydroxamic acid (BHA) is a selective collector for fluorite/calcite separation.•A larger Ca density and a higher Ca activity on fluorite {111} surface compared with calcite {104} surface.•A stronger hydrogen bonding with BHA and a weaker electrostatic repulsion with BHA−for fluorite surface.•Crystal chemistry plays a key role for the selective adsorption of BHA on fluorite.AbstractFluorite, a chief source of fluorine in the nature, usually coexists with calcite mineral in ore deposits. Worldwide, flotation techniques with a selective collector and/or a selective depressant are commonly preferred for the separation of fluorite from calcite. In the present study, an attempt was made to use benzhydroxamic acid (BHA) as a collector for the selective separation of fluorite from calcite without using any depressant. Results obtained from the flotation experiments for single mineral and mixed binary minerals revealed that the BHA has a good selective collecting ability for the fluorite when 50mg/L of BHA was used at pH of 9. The results from the zeta potential and X-ray photoelectron spectroscopy (XPS) indicated that the BHA easily chemisorbs onto the fluorite as compared to calcite. Crystal chemistry calculations showed the larger Ca density and the higher Ca activity on fluorite surface mainly account for the selective adsorption of BHA on fluorite, leading to the selective separation of fluorite from calcite. Moreover, a stronger hydrogen bonding with BHA and the weaker electrostatic repulsion with BHA−also contribute to the stronger interaction of BHA species with fluorite surface.