Thermal and electrical conductivities of epoxy resin-based composites incorporated with carbon nanotubes and TiO_2 for a thermoelectric application

摘要

For a thermoelectric application, the thermal conductivity, electrical conductivity and figure of merit of epoxy resin-based composites incorporated with carbon nanotubes and TiO_2 are investigated in this paper. First, the composite is prepared with a solution blending method. Then, the structure, thermal and electrical conductivities are characterized with experimental methods. Finally, the thermal conductivity, electrical conductivity and figure of merit are discussed. Results turn out that with an increasing content of carbon nanotube fillers, there are different changing trends of thermal and electrical conductivities because of large difference between thermal and electrical contact resistances in the composite. With the increasing filler content, the electrical conductivity increases exponentially while thermal conductivity saturates to be a constant value. Due to the large ratio of electrical to thermal conductivities, the figure of merit with 8 wt% of fillers is more than 50 times larger than that with a low content of fillers. Our results confirm that the recently proposed concept of 'electron-percolation thermal-insulator' is a feasible way to enhance the figure of merit of a polymer composite.