Effect of PbCl_2 addition on structure, OH~- content, and upconversion luminescence in Yb~(3+)/Er~(3+)-codoped germanate glasses

摘要

Yb~(3+)/Er~(3+)-codoped oxychloride germanate glasses have been synthesized by a conventional melting and quenching method. Structural properties were obtained based on Raman-spectra investigation, indicating that PbCl_2 plays an important role in the formation of the glass network and has an important influence on the phonon density and the maximum phonon energy. The Judd-Ofelt intensity parameters and quantum efficiencies were calculated based on the Judd-Ofelt theory and lifetime measurements. The enhanced upconversion luminescence intensity of Er~(3+) with increasing PbCl_2 content could not be explained only by the maximum phonon-energy change of the host glasses. For the first time, the effect of PbCl_2 addition on phonon density, OH~- content, and upconversion luminescence in oxychloride glasses has been discussed and evaluated. The results show that the effect of phonon density and OH~-content on upconversion luminescence in oxychloride glasses is much stronger than that of the decrease of the maximum phonon energy. The possible upconversion luminescence mechanisms have also been estimated and are discussed.