Sub-ppb NO_2 detection by optical feedback cavity-enhanced absorption spectroscopy with a blue diode laser

摘要

We report preliminary results on the first application of optical feedback cavity-enhanced absorption spectroscopy with a blue (411 nm) extended cavity diode laser (ECDL) for NO_2 detection. While this technique was originally developed to operate with distributed feedback diode lasers in the near infrared, it is here extended to ECDLs and applied to the blue spectral region. With a simple and compact optical setup, we demonstrate from the baseline noise a minimum detectable NO_2 concentration of 6 x 10~9 molecules/cm~3 for a single laser scan (70 ms), which extrapolated under atmospheric conditions corresponds to 200 pptv. Signal averaging should allow further lowering of this limit. Observed absorption spectra display more structure than previous spectra obtained at lower resolution by Fourier-transform spectroscopy at the same wavelength.