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首页> 外文期刊>Applied physics >Laser-based measurements of line strength, self- and pressure-broadening coefficients of the H~(35)Cl R(3) absorption line in the first overtone region for pressures up to 1 MPa
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Laser-based measurements of line strength, self- and pressure-broadening coefficients of the H~(35)Cl R(3) absorption line in the first overtone region for pressures up to 1 MPa

机译:基于激光的线形强度,H〜(35)Cl R(3)吸收线在最高压力为1 MPa时的H〜(35)Cl R(3)吸收线的测量

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摘要

A high-resolution spectrometer based on a vertical-cavity surface-emitting laser (VCSEL) was developed and used to determine the line strength S(T_0) = 12.53(11) × 10~(-21) cm~(-1)/(molec cm~(-2)) and the self-broadening coefficient γ_(HCl)~0 = 0.021787(61) cm~(-1)/atm of the R(3) absorption line in the first rovibrational overtone (2 ← 0) band of H~(35)Cl. Furthermore, the first laser-based high-pressure study on the pressure broadening of HCl by He, N_2 and O_2(γ_(N_2)~0 = 0.07292(5) cm~(-1)/atm, γ_(He)~0 = 0.02113(1) cm~(-1)/atm, γ_(O_2)~0 = 0.03978(6) cm~(-1)/atm) is presented covering pressures of up to 1 MPa. The results are compared to previously available low-pressure data.
机译:开发了一种基于垂直腔面发射激光器(VCSEL)的高分辨率光谱仪,用于确定线强度S(T_0)= 12.53(11)×10〜(-21)cm〜(-1)/ (molec cm〜(-2))和第一个振动泛音中R(3)吸收线的自扩展系数γ_(HCl)〜0 = 0.021787(61)cm〜(-1)/ atm(2← 0)H〜(35)Cl的谱带此外,首次基于激光的He,N_2和O_2(γ_(N_2)〜0 = 0.07292(5)cm〜(-1)/ atm,γ_(He)〜0的HCl压力展宽的高压研究。 = 0.02113(1)cm〜(-1)/ atm,γ_(O_2)〜0 = 0.03978(6)cm〜(-1)/ atm),涵盖了高达1 MPa的压力。将结果与先前可用的低压数据进行比较。

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  • 来源
    《Applied physics》 |2010年第2期|P.341-347|共7页
  • 作者单位

    Institute of Physical Chemistry, University of Heidelberg, INF 253, 69120 Heidelberg, Germany;

    rnInstitute of Physical Chemistry, University of Heidelberg, INF 253, 69120 Heidelberg, Germany;

    rnInstitute of Physical Chemistry, University of Heidelberg, INF 253, 69120 Heidelberg, Germany;

    rnInstitute of Physical Chemistry, University of Heidelberg, INF 253, 69120 Heidelberg, Germany;

    rnInstitute of Physical Chemistry, University of Heidelberg, INF 253, 69120 Heidelberg, Germany Physikalisch-Technische Bundesanstalt, Bundesallee 100, 38116 Braunschweig, Germany;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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