Wavelength modulation spectroscopy near 5 μm for carbon monoxide sensing in a high-pressure kerosene-fueled liquid rocket combustor

摘要

A laser absorption sensor was developed for carbon monoxide (CO) sensing in high-pressure, fuel-rich combustion gases associated with the internal conditions of hydrocarbon-fueled liquid bipropellant rockets. An absorption feature near 4.98 mu m, comprised primarily of two rovibrational lines from the P-branch of the fundamental band, was selected to minimize temperature sensitivity and spectral interference with other combustion gas species at the extreme temperatures ( 3000 K) and pressures ( 50 atm) in the combustion chamber environment. A scanned wavelength modulation spectroscopy technique (1f-normalized 2f detection) is utilized to infer species concentration from CO absorption, and mitigate the influence of non-absorption transmission losses and noise associated with the harsh sooting combustor environment. To implement the sensing strategy, a continuous-wave distributed-feedback (DFB) quantum cascade laser (QCL) was coupled to a hollow-core optical fiber for remote mid-infrared light delivery to the test article, with high-bandwidth light detection by a direct-mounted photovoltaic detector. The method was demonstrated to measure time-resolved CO mole fraction over a range of oxidizer-to-fuel ratios and pressures (20-70 atm) in a single-element-injector RP-2-GOx rocket combustor.