We report that the H_2 storage method using Ni-mediated CNTs is a viable candidate for fuel cell applications. It is demonstrated that a single Ni coated on the carbon nanotubes' (CNT) surfaces can store up to 5 H_2. In this respect, at high Ni-coverage, Ni-dispersed single-walled CNTs are considered to be capable of releasing ~10 wt, % H_2 at around room temperature. Moreover, the H_2 desorption barrier of 0.26 eV/H_2, corresponding to the desorption temperature of 328 K, is ideal for fuel cell applications.
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机译:我们报告使用镍介导的碳纳米管的H_2存储方法是燃料电池应用的可行候选者。结果表明,涂覆在碳纳米管(CNT)表面的单个Ni最多可以存储5 H_2。因此,在高Ni覆盖率的情况下,Ni分散的单壁CNT被认为能够在室温附近释放约10 wt%的H_2。此外,H_2解吸势垒为0.26 eV / H_2,对应于328 K的解吸温度,是燃料电池应用的理想选择。
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