Precise measurement of single carbon nanocoils using focused ion beam technique

摘要

We have developed a precise resistivity measurement system for quasi-one-dimensional nanomaterials using a focused ion beam. The system enables the resistivity of carbon nanocoils (CNCs) to be measured and its dependence on coil geometry to be elucidated. At room temperature, the resistivity of CNCs tended to increase with coil diameter, while that of artificially graphitized CNCs remained constant. These contrasting behaviors indicate coil-diameter-induced enhancement in structural disorder internal to CNCs. Low-temperature resistivity measurements performed on the CNCs revealed that electron transport through the helical axis is governed by the variable range hopping mechanism. The characteristic temperature in variable range hopping theory was found to systematically increase with coil diameter, which supports our theory that the population of sp~2-domains in CNCs decreases considerably with coil diameter.