Zeolitisation of perlite fines: mineralogical characteristics of the end products and mobilization of chemical elements

摘要

This study examines the synthetic zeolites produced from perlite waste. Zeolitisation was carred out in autoclaves with NaOH solutions at l00deg--l40deg.C. The volcanic glass was converted to zeolite-P_c, zeolite--V and hydroxysodalite. The rate of conversion of the glass and the transformation of zeolites depended on temperature, time and NaOH concentration. The principal chemical changes observed between the initial glass and the end product involved the removal of Si and K and the uptake of Na. The amount of Si and K released increased with increasing alkalinity, reaching a steady state in the whole temperature range. The amount of Si at the steady state decreased with increasing temperature, while that of K followed an opposite trend. Therefore, the SiO_2fAI_2O_3 ratio of the solid phase at steady state increased with increasing temperature. The amount of Na taken up increased with increasing alkalinity, increasing the Na_2O:Al_2O_3 ratio and decreasing the SiO_2:Na_2O ratio of the solid phase, as reaction progresses. The crystallinity of zeolite--P_c increased with the amount of Na_2O present in solution up to a maximum value, then decreased rapidly. The zeolite-P_c initially formed had a high SiO_2:Al_2O_3 ratio, which then decreased gradually until zeolite-V was formed. Both zeolites were replaced by hydroxysodalite at higher alkalinity. Zeolite--V was metastable and converted to zeolite-P_c after prolonged exposure to the atmosphere. The average cation exchange capacity (CEC) of the zcolite products is 3.0 meq/g and equilibrium was attained very fast, suggesting that the products can be