CO_2 capture by kaolinite and its adsorption mechanism

摘要

The low-cost and naturally abundant clay mineral kaolinite was studied for use an adsorbent for CO_2 capture. Samples of kaolinite were subjected to acid treatments to improve their textural properties, namely, its surface area and pore volume. It was found that the kaolinite sample treated with 3 M H_2SO_4 for 10 h reaction exhibited the highest Brunauer-Emmett-Teller (BET) surface area (18.9-74.3 m~2/g) and pore volume (0.11-0.31 cm~3/g). The CO_2 adsorption capacity of kaolinite, which was ～0 mg-CO_2/g-sorbent at 25 ℃, increased to 3.4 mg-CO_2/g-sorbent after the acid treatment. Moreover, it was found that the CO_2 adsorption capacity of kaolinite was greater at room temperature than at higher temperatures. The CO_2 adsorption by kaolinite, which was investigated using X-ray diffraction analysis, Fourier transform infrared spectroscopy, and CO_2 adsorption isotherm measurements, was found to be mainly attributable to physical adsorption.