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PROCESS FOR CAPTURING CO_2 FROM A CO_2 -CONTAINING GAS STREAM USING A THERMORESPONSIVE COPOLYMER

机译:使用热敏性共聚物从含CO_2的天然气流中捕获CO_2的方法

摘要

The present invention, in the vessel up to a temperature T1 CO 2 of the absorbent step-by step of contacting a gas containing stream resulting in the absorption of CO 2, the CO 2 - - absorber and CO 2 absorbent is a polymer which is soluble in an aqueous medium Wherein the polymer is a thermally reactive copolymer comprising an amine monomer dispersed through a copolymer; And CO 2 in the vessel up to a temperature T2 - was added to the desorption step in containing absorbent comprising the steps of causing the release of CO 2; CO 2 containing - as a way to capture the CO 2 from the gas containing stream, wherein T1 is the maximum The LCST of the thermally reactive polymer at the time of CO 2 loading and the T2 is at least the LCST of the thermally reactive polymer at the time of minimum CO 2 loading and the CO 2 absorbent further comprises an amine component that is soluble in the aqueous medium. The use of specific polymers in the present invention in which the amine monomer is dissolved in the aqueous medium at T1 and dispersed through the copolymer in combination with the amine component shows improved total CO 2 sorption and high absorption rates, Thereby making it possible to use an absorption reactor.
机译:本发明,在容器中直到吸收剂的温度T1为CO 2 ,逐步接触含气体流,导致CO 2的吸收, CO 2 -吸收剂和CO 2 吸收剂是可溶于水介质的聚合物,其中该聚合物是热活性共聚物,其包含分散在共聚物中的胺单体。然后将容器中温度最高为T2-的CO 2 添加到包含吸收剂的解吸步骤中,该吸收剂包括引起CO 2释放的步骤; CO 2 包含-一种从含气流中捕获CO 2 的方式,其中T1为最大值CO 2 <时热反应性聚合物的LCST / Sub>负载,并且T2至少是最小CO 2 负载时热反应性聚合物的LCST,并且CO 2 吸收剂还包含胺成分可溶于水性介质。在胺中将胺单体在T1溶解在水性介质中并与胺组分一起分散在共聚物中的本发明中的特定聚合物的使用显示出改进的总CO 2 吸附和高吸收率因此,可以使用吸收反应器。

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