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Synthesis and characterization of magnetic halloysite-iron oxide nanocomposite and its application for naphthol green B removal

机译:磁性埃洛石-氧化铁纳米复合材料的合成,表征及其在萘酚绿B去除中的应用

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In the present work, a magnetic nanoadsorbent was prepared by incorporating magnetic iron oxide nanoparticles (Fe3O4) on the surface of halloysite nanotubes. The structure and morphology of the synthesized nanocomposite were investigated by using of FT-IR and field emission-scanning electron microscope. This nanoadsorbent was successfully applied for removal of naphthol green B from the aqueous solutions. Kinetic studies show the adsorption of naphthol green B on the surface of adsorbent could be characterized by the pseudo-second order model. Also, investigation of adsorption isotherms showed that the Langmuir model fitted better than the Freundlich model and naphthol green B forms a mono-layer on the surface of nanoadsorbent. Furthermore, spectrophotometric determinations for dye were done at lambda = 265 nm and the results show the linearity in the range of 1.0-50 mu g mL(-1). (C) 2016 Elsevier B.V. All rights reserved.
机译:在目前的工作中,通过将磁性氧化铁纳米颗粒(Fe3O4)掺入埃洛石纳米管的表面来制备磁性纳米吸附剂。利用红外光谱和场发射扫描电子显微镜研究了合成的纳米复合材料的结构和形貌。该纳米吸附剂已成功用于从水溶液中去除萘酚绿B。动力学研究表明,萘酚绿B在吸附剂表面的吸附可以用拟二级模型表征。另外,对吸附等温线的研究表明,Langmuir模型比Freundlich模型拟合得更好,并且萘酚绿B在纳米吸附剂表面形成单层。此外,在λ= 265 nm处进行分光光度法测定染料,结果表明线性范围为1.0-50μg mL(-1)。 (C)2016 Elsevier B.V.保留所有权利。

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