Enantioselective Synthesis of Trifluoromethyl-Substituted 2-Isoxazolines: Asymmetric Hydroxylamine/Enone Cascade Reaction†

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• 来源
  《Angewandte Chemie International Edition》 |2010年第33期|p.5762-5766|共5页
• 作者

  Kazutaka Matoba; Hiroyuki Kawai; Tatsuya Furukawa; Akihiro Kusuda; Etsuko Tokunaga; Shuichi Nakamura Dr.; Motoo Shiro Dr.; Norio Shibata Prof.;

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• 作者单位

  Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555 (Japan), Fax: (+81) 52-735-5442;

  Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555 (Japan), Fax: (+81) 52-735-5442;

  Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555 (Japan), Fax: (+81) 52-735-5442;

  Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555 (Japan), Fax: (+81) 52-735-5442;

  Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555 (Japan), Fax: (+81) 52-735-5442;

  Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555 (Japan), Fax: (+81) 52-735-5442;

  Rigaku Corporation, 3-9-12 Mastubara-cho, Akishima Tokyo 196-8666 (Japan);

  Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555 (Japan), Fax: (+81) 52-735-5442;

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• 关键词

  asymmetric catalysis; fluorine; heterocycles; organocatalysis; phase-transfer catalysis;

  机译：不对称催化氟杂环有机催化相转移催化;