The Elusive Enamine Intermediate in Proline-Catalyzed Aldol Reactions: NMR Detection, Formation Pathway, and Stabilization Trends†

li id=au1Markus#x2005; B. Schmid li id=au2Kirsten Zeitler Dr. li id=au3Ruth#x2005; M. Gschwind Prof.#x2005; Dr.

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The Elusive Enamine Intermediate in Proline-Catalyzed Aldol Reactions: NMR Detection, Formation Pathway, and Stabilization Trends†

机译：脯氨酸催化的醛醇缩合反应中难以捉摸的烯胺中间体：NMR检测，形成途径和稳定趋势†

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《Angewandte Chemie International Edition》 |2010年第29期|p.4997-5003|共7页
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li id=au1Markus#x2005; B. Schmid li id=au2Kirsten Zeitler Dr. li id=au3Ruth#x2005; M. Gschwind Prof.#x2005; Dr.;
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aldol reaction; enamines; NMR spectroscopy; organocatalysis; proline catalysis;

机译：醛醇缩合反应;烯胺;核磁共振光谱;有机催化;脯氨酸催化;

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1. Enamine versus Oxazolidinone: What Controls Stereoselectivity in Proline-Catalyzed Asymmetric Aldol Reactions?† [J] . li id=au1Akhilesh#x2005, K. Sharma li id=au2Raghavan#x2005, B. Sunoj Prof.#x2005, Angewandte Chemie . 2010,第36期

机译：烯胺与恶唑烷酮：脯氨酸催化的不对称醛醇缩合反应中控制立体选择性的因素是什么？†
2. Enamine versus Oxazolidinone: What Controls Stereoselectivity in Proline-Catalyzed Asymmetric Aldol Reactions?† [J] . Akhilesh#x2005, K. Sharma Raghavan#x2005, B. Sunoj Prof.#x2005, Angewandte Chemie International Edition . 2010,第36期

机译：烯胺与恶唑烷酮：脯氨酸催化的不对称醛醇缩合反应中控制立体选择性的因素是什么？†
3. Enamine versus Oxazolidinone: What Controls Stereoselectivity in Proline-Catalyzed Asymmetric Aldol Reactions? [J] . Akhilesh K. Sharma, Raghavan B. Sunoj Angewandte Chemie . 2010,第36期

机译：烯胺与恶唑烷酮：脯氨酸催化的不对称醛醇缩合反应中控制立体选择性的因素是什么？
4. Theoretical investigation on the role of amine bases in stabilizing the key intermediate of proline enamine carboxylate in proline-catalyzed asymmetric reactions [C] . Changke Tian, Aiping Fu, Chengyan Zhao International Conference on Applied Sciences, Engineering and Technology . 2014

机译：胺基碱在脯氨酸催化不对称反应中脯氨酸烯胺羧酸盐关键中间体作用的理论研究
5. Trapping the Elusive Aza-Oxyallylic Cation Intermediate: Aza-[4+3] Cycloaddition Reactions and their Application Toward Target Directed Synthesis. [D] . Barnes, Korry Lee. 2014

机译：捕集难以捉摸的氮杂-羟基烯丙基阳离子中间体：氮杂-[4 + 3]环加成反应及其在目标直接合成中的应用。
6. Enamine/Dienamine and Brønsted Acid Catalysis:Elusive Intermediates Reaction Mechanisms and Stereoinduction ModesBased on in Situ NMR Spectroscopy and Computational Studies [O] . Polyssena Renzi, Johnny Hioe, Ruth M. Gschwind, -1

机译：烯胺/二胺和布朗斯台德酸催化：难以捉摸的中间体反应机理和立体诱导模式基于原位NMR光谱和计算研究
7. NMR Spectroscopic Characterization of a b-(1, 4)-Glycosidase along Its Reaction Pathway: Stabilization upon Formation of the Glycosyl-Enzyme Intermediate [O] . -1

机译：沿其反应途径的B-（1,4） - 糖苷酶的NMR光谱表征：糖基酶中间体形成时稳定化

The Elusive Enamine Intermediate in Proline-Catalyzed Aldol Reactions: NMR Detection, Formation Pathway, and Stabilization Trends†

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