An Adaptation of Kubista's Method for Spectral Curve Deconvolution

摘要

A chemometric approach to spectral curve deconvolution is described, evaluated, and applied to micellar systems. The technique is based on the method of principal component analysis of a spectral matrix followed by transformation of the abstract vectors into real spectra and concentrations. The approach reported here is similar to that of Kubista et al.(Anal. Chem. 1993, 65, 994-998). In the present study, however, more spectral information is known about the system of interest.