Outstanding Low Temperature Thermoelectric Power Factor from Completely Organic Thin Films Enabled by Multidimensional Conjugated Nanomaterials

摘要

In an effort to create a paintable/printable thermoelectric material, comprised exclusively of organic components, polyaniline (PANi), graphene, and double-walled nanotube (DWNT) are alternately deposited from aqueous solutions using the layer-by-layer assembly technique. Graphene and DWNT are stabilized with an intrinsically conductive polymer, poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS). An 80 quadlayer thin film (approximate to 1 mu m thick), comprised of a PANi/graphene-PEDOT:PSS/PANi/DWNTPEDOT: PSS repeating sequence, exhibits unprecedented electrical conductivity (sigma approximate to 1.9 x 10(5) S m(-1)) and Seebeck coefficient (S approximate to 120 mu V K-1) for a completely organic material. These two values yield a thermoelectric power factor (PF = S-2 sigma(-1)) of 2710 mu W m(-1) K-2, which is the highest value ever reported for a completely organic material and among the highest for any material measured at room temperature. These outstanding properties are attributed to the highly ordered structure in the multilayer assembly. This water-based thermoelectric nanocomposite is competitive with the best inorganic semiconductors (e.g., bismuth telluride) at room temperature and can be applied as a coating to any flexible surface (e.g., fibers in clothing). For the first time, there is a real opportunity to harness waste heat from unconventional sources, such as body heat, to power devices in an environmentally-friendly way.