Pore and Heteroatom Engineered Carbon Foams for Supercapacitors

摘要

Carbonaceous materials are attractive supercapacitor electrode materials due to their high electronic conductivity, large specific surface area, and low cost. Here, a unique hierarchical porous N,O,S-enriched carbon foam (KNOSC) with high level of structural complexity for supercapacitors is reported. It is fabricated via a combination of a soft-template method, freeze-drying, and chemical etching. The carbon foam is a macroporous structure containing a network of mesoporous channels filled with micropores. It has an extremely large specific surface area of 2685 m(2) g(-1). The pore engineered carbon structure is also uniformly doped with N, O, and S. The KNOSC electrode achieves an outstanding capacitance of 402.5 F g(-1) at 1 A g(-1) and superior rate capability of 308.5 F g(-1) at 100 A g(-1). The KNOSC exhibits a Bode frequency at the phase angle of -45 degrees of 18.5 Hz, which corresponds to a time constant of 0.054 s only. A symmetric supercapacitor device using KNOSC as electrodes can be charged/discharged within 1.52 s to deliver a specific energy density of 15.2 W h kg(-1) at a power density of 36 kW kg(-1). These results suggest that the pore and heteroatom engineered structures are promising electrode materials for ultrafast charging.