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首页> 外文期刊>Acta Physica Polonica >Water Hydrogen Bonds Study by Opto-Magnetic Fingerprint Technique
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Water Hydrogen Bonds Study by Opto-Magnetic Fingerprint Technique

机译:电磁指纹技术研究水氢键

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摘要

Hydrogen bond has dual property, classical (electrostatic interaction based on Coulomb's law) and quantum (wave function based on Schroedinger equation). Since Planck's constant is one of the main criteria for decision which process is quantum, or how much is close to be quantum, we use electrical and magnetic forces of valence electrons, as point of departure, to develop method for opto-magnetic fingerprint of matter. During the study of different type of matter we observed phenomena from spectral convolution data of digital images which characterize matter from both covalent and non-covalent bonding. Since water is matter that is most abundant with hydrogen bonds, we present results of 18.2 MΩ water investigation on different temperature and under influence of constant and variable magnetic fields by opto-magnetic method. Bearing in mind that Linus Pauling, in his book Nature of the Chemical Bond (Cornel University Press, 1939), for the first time presented the systematic concept of the hydrogen bond to the molecular world and its machinery, this paper is written in honor to him and 70th anniversary of one of the most important scientific paradigm.
机译:氢键具有双重性质,经典性质(基于库仑定律的静电相互作用)和量子性质(基于Schroedinger方程的波函数)。由于普朗克常数是决定哪个过程是量子过程或接近量子过程的主要标准之一,因此我们以价电子的电磁力作为出发点,来开发物质的光磁指纹方法。 。在研究不同类型的物质的过程中,我们从数字图像的光谱卷积数据中观察到了现象,这些数据通过共价键和非共价键表征了物质。由于水是具有氢键最多的物质,因此我们通过光磁方法介绍了在不同温度下以及在恒定和可变磁场的影响下进行的18.2MΩ水研究的结果。考虑到莱纳斯·鲍林(Linus Pauling)在他的《化学键的性质》(康奈尔大学出版社,1939年)一书中首次提出了氢键在分子世界及其机械中的系统概念,为纪念他和70周年是最重要的科学范例之一。

著录项

  • 来源
    《Acta Physica Polonica 》 |2010年第5期| P.777-781| 共5页
  • 作者单位

    University of Belgrade Kraljice Marije 16, 11120 Belgrade, Serbia;

    Galenika Institute, Batajnieki drum bb, 11080 Belgrade, Serbia;

    rnUniversity of Belgrade Kraljice Marije 16, 11120 Belgrade, Serbia;

    rnUniversity of Belgrade Kraljice Marije 16, 11120 Belgrade, Serbia;

    rnUniversity of Belgrade Kraljice Marije 16, 11120 Belgrade, Serbia;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    visible spectra; polarization; imaging and optical processing;

    机译:可见光谱偏振;成像和光学处理;

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