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Development and Applications of MOFs Derivative One-Dimensional Nanofibers via Electrospinning: A Mini-Review

机译:MOFs一维纳米纤维的静电纺丝技术开发与应用:综述。

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摘要

Metal organic frameworks (MOFs) have been exploited for various applications in science and engineering due to the possibility of forming different mesoscopic frameworks and pore structures. To date, further development of MOFs for practical applications in areas such as energy storage and conversion have encountered tremendous challenge owing to the unitary porous structure (almost filled entirely with micropores) and conventional morphology (e.g., sphere, polyhedron, and rod shape). More recently, one-dimensional (1D) MOFsanofibers composites emerged as a new molecular system with highly engineered novel structures for tailored applications. In this mini-review, the recent progress in the development of MOFs-based 1D nanofibers via electrospinning will be elaborated. In particular, the promising applications and underlying molecular mechanism of electrospun MOF-derived carbon nanofibers are primarily focused and analyzed here. This review is instrumental in providing certain guiding principles for the preparation and structural analysis of MOFs/electrospun nanofibers (M-NFs) composites and electrospun MOF-derived nanomaterials.
机译:由于可能形成不同的介观框架和孔结构,因此金属有机骨架(MOF)已在科学和工程中用于各种应用。迄今为止,由于单一的多孔结构(几乎完全充满了微孔)和常规的形态(例如球形,多面体和棒状),在诸如能量存储和转换等领域的实际应用中,MOF的进一步发展遇到了巨大的挑战。最近,一维(1D)MOF /纳米纤维复合材料作为一种具有高度工程化的新颖结构的新分子系统出现,可用于量身定制的应用。在此小型审查中,将详细阐述通过电纺技术开发基于MOF的1D纳米纤维的最新进展。特别是,电纺MOF衍生的碳纳米纤维的有前途的应用和潜在的分子机理在这里主要集中和分析。这项审查有助于为MOF /电纺纳米纤维(M-NFs)复合材料和电纺MOF衍生的纳米材料的制备和结构分析提供某些指导原则。

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