Brightly Fluorescent Zinc-DopedRed-Emitting Carbon Dots for the Sunlight-InducedPhotoreduction of Cr(VI) to Cr(III)

摘要

The present finding deals with a simple and low-cost fabrication of surface-passivated, brightly fluorescent zinc-oxide-decorated, red-emitting excitation-independent ultrafluorescent CDs, denoted as “CZnO-Dots”. Surface doping of zinc oxide significantly improved the quantum yield by up to ∼72%, and these brightly fluorescent red-emitting CZnO-Dots have been employed for the aqueous-phase photoreduction of 100 ppm hexavalent chromium(VI) to trivalent chromium(III) under the influence of sunlight irradiation. The overall utility of the prepared CZnO-Dots can be ascertained by their recyclability over seven cycles.