Clay-Based Nanocomposites as Recyclable Adsorbenttoward Hg(II) Capture: Experimental and Theoretical Understanding

摘要

Here, we report the development of inorganic–organic hybrid nanocomposites through selective modification of the negative outer surfaces of halloysite nanoclays with two different organosilanes having primary or secondary amine sites to be explored them as novel and cost-effective adsorbents for the extraction of toxic inorganic contaminants from aqueous solution. They possess excellent selectivity for the adsorption of mercury, which shows monolayer molecular adsorption over the nanocomposites. The adsorption kinetics of Hg(II) is very fast and follows pseudo-second-order model compared to pseudo-first-order model. A combined experimental and theoretical study demonstrated that Hg(II) uptake by these nanocomposites is highly favorable and spontaneous up to 40 °C, and beyond this temperature, the uptake capacity gradually reduced. Temperature-dependent adsorption study exhibits endothermicity at low temperature (≤40 °C) and exothermicity beyond 40 °C. pH-dependent adsorption study showed their high uptake capacity until pH 7, which reduced at alkaline pH.All of the nanocomposites hold excellent adsorption capacity evenat low concentration of adsorbate, along with multicycle sorptioncapability. The outstanding adsorption capacity as well as the easysynthetic route to achieve these nanocomposites may attract researchersto develop low-cost adsorbents to capture toxic metals, which in turnregulate the permissible limit of these toxic metals in drinking water.