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Surface degradation effects of carbonated soft drink on a resin based dental compound

机译:碳酸软饮料对树脂牙科化合物的表面降解效应

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摘要

Dental compounds and restorative materials undergo surface degradation and erosion from exposure to a variety of dietary substances. In this study we investigated changes in the surface properties of Rebaron, a hard denture reline material (HDRM), following timed immersion in carbonated soft drinks to determine its durability in a common acidic environment. Samples were prepared and immersed in a carbonated soft drink (or its components) for 6, 12, or 24 h. Surface structure and mechanical properties were characterized using Atomic Force Microscopy (AFM). Raman spectroscopy was used to identify changes in the HDRM surface chemistry following exposure to the test solutions. AFM revealed that prolonged exposure led to pit formation and a subsequent increase in surface roughness, from 302.02 ± 30.20 to 430.59 ± 15.07 nm Ra, following a 24 h exposure. Young's modulus values decreased from 9.3 ± 7.0 to 0.53 ± 0.26 GPa under the same conditions, demonstrating a softening and embrittlement of the HDRM sample. Raman results revealed that immersion in the carbonated soft drink or acidic solution changed the nature of the HDRM structure, converting the HDRM surface chemistry from primarily hydrophobic to hydrophilic. Our study indicates that sustainability and durability of Rebaron HDRM are significantly reduced by prolonged exposure to carbonated (acidic) soft drink, resulting in deformation and degradation of the material surface.
机译:牙科化合物和恢复材料从暴露于各种膳食物质中进行表面降解和侵蚀。在这项研究中,在碳酸化软饮料中定时浸泡后,在碳酸化软饮料中沉浸在碳酸化软饮料中的耐牙本质型材料(HDRM)表面性质的变化以确定其在普通酸性环境中的耐久性。制备样品并浸入碳酸化软饮料(或其组分)中6,12或24小时。使用原子力显微镜(AFM)表征表面结构和机械性能。拉曼光谱法用于鉴定暴露于试验溶液后HDRM表面化学的变化。 AFM透露,延长的暴露导致坑形成和随后的表面粗糙度的增加,从302.02±30.20至430.59±15.07nm Ra暴露后,从302.02±30.20至430.59±15.07nm Ra。在相同条件下,杨氏模量值从9.3±7.0至0.53±0.26GPa降低,展示了HDRM样品的软化和脆化。拉曼结果表明,碳酸化软饮料或酸性溶液中的浸泡改变了HDRM结构的性质,将HDRM表面化学从主要疏水转化为亲水性。我们的研究表明,通过长时间暴露于碳酸(酸性)软饮料,Rebaron HDRM的可持续性和耐久性显着降低,导致材料表面的变形和降解。

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