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Fabrication of a Novel Antifouling Polysulfone Membrane with in Situ Embedment of Mxene Nanosheets

机译:原位嵌入二甲苯纳米片的新型防污聚砜膜的制备

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摘要

Membrane fouling is still a critical issue for the application of ultrafiltration, which has been widely used in water treatment due to its efficiency and simplicity. In order to improve the antifouling property, a new 2D material MXene was used to fabricate composite ultrafiltration membrane with the approach of in situ embedment during the phase inversion process in this study. Scanning electron microscopy (SEM), atomic force microscopy (AFM), thermogravimetric analysis (TGA), energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR), water contact angle, bovine serum albumin rejection and porosity measurements were utilized to characterize the prepared membranes. Due to the hydrophilicity of the MXene, the composite membranes obtained higher hydrophilicity, confirmed by the decreased water contact angle. All the modified membranes had a high bovine serum albumin rejection above 90% while that of the pristine polysulfone membrane was 77.48%. The flux recovery ratio and the reversible fouling ratio of the membranes were also improved along with the increasing content of the MXene. Furthermore, the highest flux recovery ratio could also reach 76.1%. These indicated the good antifouling properties of MXene composite membranes. The enhanced water permeability and protein rejection and excellent antifouling properties make MXene a promising material for antifouling membrane modification.
机译:膜结垢仍然是应用超滤的关键问题,超滤由于其效率和简便性而已广泛用于水处理中。为了提高防污性能,本研究采用一种新型的二维材料MXene,在相转化过程中采用原位包埋的方法制备复合超滤膜。利用扫描电子显微镜(SEM),原子力显微镜(AFM),热重分析(TGA),能量色散光谱(EDS),傅里叶变换红外光谱(FTIR),水接触角,牛血清白蛋白截留率和孔隙率测量来表征准备好的膜。由于MXene的亲水性,复合膜获得了更高的亲水性,这通过减小的水接触角证实。所有改性膜的牛血清白蛋白截留率均高于90%,而原始聚砜膜的截留率为77.48%。膜的通量回收率和可逆结垢率也随着MXene含量的增加而提高。此外,最高的焊剂回收率也可以达到76.1%。这些表明MXene复合膜具有良好的防污性能。增强的水渗透性和蛋白质排斥性以及出色的防污性能使MXene成为用于防污膜改性的有前途的材料。

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