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Data of XPS in incorporating the platinum complexes dopant on the surface of Ag3PO4 photocatalyst

机译:XPS在Ag3PO4光催化剂表面掺入铂络合物掺杂剂的数据

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摘要

These data inform about the XPS profile of Ag4d, P2p, and O1s from the samples of Ag PO , defect-Ag PO , Ag PO /PtCl and defect-Ag PO /PtCl which were denoted as AP, DAP, AP/Pt, and DAP/Pt, respectively. These samples were made by co-precipitation method using the starting material of silver nitrate (AgNO ), disodium hydrogen phosphate dodecahydrate (Na HPO .12H O), and hexachloroplatinic acid hexahydrate (H PtCl .6H O) for platinum complexes dopant. The water solution and mixed water-ethanol solution for dissolving the AgNO were used for free-defect and defect samples, respectively. The Ag4d, P2p, and O1s of these samples were investigated using the XPS. The deconvolutions of O1s peak were analyzed using the software of XPSPEAK Version 4.1. The modification of Ag PO by defect and platinum complexes dopant had changed the curve profile of Ag4d, P2p and O1s. Two types of oxygen of O-1 and O-2 were observed in O1s spectrum. The ratios of O-2/O-1 with the value of 0.25, 0.32, 0.49 and 0.51 were found in the sample of AP, DAP, AP/Pt, and DAP/Pt, respectively. These data are related to the research article “The surface modification of Ag PO using anionic platinum complexes for enhanced visible-light photocatalytic activity” [1].
机译:这些数据可从Ag PO,缺陷Ag PO,Ag PO / PtCl和缺陷Ag PO / PtCl的样品中分别表示为AP,DAP,AP / Pt和Ag4d,P2p和O1的XPS分布图DAP / Pt分别。这些样品是使用硝酸银(AgNO),磷酸氢二钠十二水合物(Na HPO .12H O)和六氯铂酸六水合物(H PtCl .6H O)的起始原料通过共沉淀法制备的,用于制备铂络合物掺杂剂。溶解AgNO的水溶液和水-乙醇混合溶液分别用于自由缺陷和缺陷样品。使用XPS研究了这些样品的Ag4d,P2p和O1。使用XPSPEAK版本4.1的软件分析O1峰的反卷积。缺陷和铂配合物掺杂剂对Ag PO的改性改变了Ag4d,P2p和O1s的曲线轮廓。在O1s光谱中观察到O-1和O-2两种氧。在AP,DAP,AP / Pt和DAP / Pt样品中分别发现O-2 / O-1的比值为0.25、0.32、0.49和0.51。这些数据与研究文章“使用阴离子铂络合物对Ag PO进行表面改性以增强可见光的光催化活性”有关[1]。

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