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Synthesis and enhanced photocatalytic performance of 0D/2D CuO/tourmaline composite photocatalysts

机译:0D / 2D CuO /电气石复合光催化剂的合成及增强的光催化性能

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摘要

Photocatalysis is considered to be a green and promising technology for transforming organic contaminants into nontoxic products. In this work, a CuO/tourmaline composite with zero-dimensional/two-dimensional (0D/2D) CuO architecture was successfully obtained via a facile hydrothermal process, and its photocatalytic activity was evaluated by the degradation of methylene blue (MB). Surface element valence state and molecular vibration characterization revealed that CuO chemically interacted with tourmaline via Si–O–Cu bonds. The specific surface area of the CuO/tourmaline composite (23.60 m g ) was larger than that of the pristine CuO sample (3.41 m g ). The CuO/tourmaline composite exhibited excellent photocatalytic activity for the degradation of MB, which was ascribed to the increase in the quantity of the adsorption-photoreactive sites and the efficient utilization of the photoinduced charge carriers. This study provides a facile strategy for the construction of 0D/2D CuO structures and the design of tourmaline-based functional composite photocatalysts for the treatment of organic contaminants in water.
机译:光催化被认为是将有机污染物转化为无毒产品的绿色和有前途的技术。在这项工作中,通过简便的水热工艺成功地获得了具有零维/二维(0D / 2D)CuO结构的CuO /电气石复合材料,并通过亚甲基蓝(MB)的降解评估了其光催化活性。表面元素的价态和分子振动特征表明,CuO通过Si–O–Cu键与电气石化学相互作用。 CuO /电气石复合材料的比表面积(23.60 m g)大于原始CuO样品的比表面积(3.41 m g)。 CuO /电气石复合材料对MB的降解表现出优异的光催化活性,这归因于吸附光反应位点数量的增加和光诱导电荷载体的有效利用。该研究为0D / 2D CuO结构的构建和电气石基功能性复合光催化剂的设计提供了一种简便的策略,用于处理水中的有机污染物。

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