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Correlated Diffusion of Colloidal Particles near a Liquid-Liquid Interface

机译:胶体颗粒在液-液界面附近的相关扩散

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摘要

Optical microscopy and multi-particle tracking are used to investigate the cross-correlated diffusion of quasi two-dimensional colloidal particles near an oil-water interface. The behaviors of the correlated diffusion along longitudinal and transverse direction are asymmetric. It is shown that the characteristic length for longitudinal and transverse correlated diffusion are particle diameter and the distance from particle center to the interface, respectively, for large particle separation . The longitudinal and transverse correlated diffusion coefficient and are independent of the colloidal area fraction when , which indicates that the hydrodynamic interactions(HIs) among the particles are dominated by HIs through the surrounding fluid for small . For high area fraction , the power law exponent for the spatial decay of begins to decrease, which suggests the HIs are more contributed from the 2D particle monolayer self for large .
机译:光学显微镜和多粒子跟踪技术用于研究油水界面附近准二维胶体粒子的互相关扩散。沿纵向和横向的相关扩散行为是不对称的。结果表明,对于大的颗粒分离,纵向和横向相关扩散的特征长度分别是粒径和从颗粒中心到界面的距离。纵向和横向的扩散系数相关,并且与胶体面积分数无关,这表明粒子之间的流体动力相互作用(HIs)通过HIs通过周围流体占主导。对于高面积分数,的空间衰减的幂律指数开始减小,这表明HI对较大的2D粒子单层自身贡献更大。

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