Revisiting of Benzophenone Ketyl Still: Use of a SodiumDispersion for the Preparation of Anhydrous Solvents

摘要

A facile generation of organic solvents of anhydrous grade can be performed by distillation from sodium–benzophenone ketyl, which is prepared from commercial sodium dispersion and benzophenone. The distilled tetrahydrofuran, diethyl ether, hexane, 1,2-dimethoxyethane, and 1,4-dioxane with water contents less than 10 ppm were obtained by a simple protocol. Safe treatment of the distillation residue also was simply achieved by the addition of methanol. The protocol suits for providing a small amount of an anhydrous solvent at the laboratory scale.