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Electroconductive PEDOT:PSS-based hydrogel prepared by freezing-thawing method

机译:冻融法制备导电PEDOT:PSS基水凝胶

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摘要

Biopolymer-based composition with adding of conductive polymer poly-(3,4-ethylenedioxythiophene) polystyrenesulfonate (PEDOT PSS) was made by mixing of iota-carrageenan (CRG), polyvinyl alcohol (PVA) and PEDOT PSS followed by freezing/thawing cycles. The method is environmentally friendly and based on the formation of polymer matrix upon of mixing CRG, PVA and PEDOT PSS and formation of porous physical gel due to freezing/thawing cycles. It is necessary to mention that all components are well-known as biocompatible materials. The resulting material is stable in water and also has swelling capability both in distilled water and physiological solutions. Structure of material was characterized by means of X-ray diffraction, optical and electron microscopy. Electrophysical investigations also were performed. The conductivity of the gel immersed in distilled water is comparable with the dry gel value and close to 0.01 [S/cm].
机译:通过将碘-角叉菜胶(CRG),聚乙烯醇(PVA)和PEDOT PSS混合,然后进行冷冻/融化循环,制得添加导电聚合物聚(3,4-乙撑二氧噻吩)聚苯乙烯磺酸盐(PEDOT PSS)的生物聚合物基组合物。该方法是环境友好的,并且基于在混合CRG,PVA和PEDOT PSS时形成聚合物基质以及由于冷冻/融化循环而形成的多孔物理凝胶的方法。必须提及的是,所有成分都是众所周知的生物相容性材料。所得材料在水中稳定,并且在蒸馏水和生理溶液中也具有溶胀能力。通过X射线衍射,光学和电子显微镜表征材料的结构。还进行了电物理检查。浸入蒸馏水中的凝胶的电导率与干凝胶值相当,接近0.01 [S / cm]。

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