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Effects of Photochromic Furan-Based Diarylethenes on Gold Nanoparticles Aggregation

机译:光致变色呋喃基二硫醚对金纳米粒子聚集的影响

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摘要

The photochromic properties of furan-based diarylethenes and their interaction with citrate-capped gold nanoparticles were investigated by ultraviolet/visible absorption spectroscopy and transmission electron microscopy. We identified the optimal concentration of diarylethenes in water-ethanol mixture required for stability of colloidal systems. Nanoparticles coupled with diarylethene derivatives exhibit a new surface plasmon resonance band coming from their aggregation. We analyzed the effects of functional side-chain groups on aggregation process. These results can be considered as a basis for further designing of novel hybrid nanomaterials and optoelectronic elements.Electronic supplementary materialThe online version of this article (doi:10.1186/s11671-017-2044-6) contains supplementary material, which is available to authorized users.
机译:通过紫外/可见吸收光谱和透射电子显微镜研究了呋喃基二硫醚的光致变色性质及其与柠檬酸盐封端的金纳米粒子的相互作用。我们确定了胶体系统稳定性所需的水-乙醇混合物中的最佳二芳烃浓度。结合二芳基乙烯衍生物的纳米颗粒表现出来自其聚集的新的表面等离子体共振带。我们分析了功能性侧链基团对聚集过程的影响。这些结果可被视为进一步设计新型混合纳米材料和光电元件的基础。电子补充材料本文的在线版本(doi:10.1186 / s11671-017-2044-6)包含补充材料,授权用户可以使用。 。

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