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Chemically Propelled Motors Navigate Chemical Patterns

机译:化学推进马达引导化学模式

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摘要

Very small synthetic motors that use chemical reactions to drive their motion are being studied widely because of their potential applications, which often involve active transport and dynamics on nanoscales. Like biological molecular machines, they must be able to perform their tasks in complex, highly fluctuating environments that can form chemical patterns with diverse structures. Motors in such systems can actively assemble into dynamic clusters and other unique nonequilibrium states. It is shown how chemical patterns with small characteristic dimensions may be utilized to suppress rotational Brownian motions of motors and guide them to move along prescribed paths, properties that can be exploited in applications. In systems with larger pattern length scales, domains can serve as catch basins for motors through chemotactic effects. The resulting collective motor dynamics in such confining domains can be used to explore new aspects of active particle collective dynamics or promote specific types of active self‐assembly. More generally, when chemically self‐propelled motors operate in far‐from‐equilibrium active chemical media the variety of possible phenomena and the scope of their potential applications are substantially increased.
机译:由于其潜在的应用,使用化学反应来驱动其运动的非常小的合成电动机正在得到广泛研究,这些应用通常涉及纳米级的主动运输和动力学。像生物分子机器一样,它们必须能够在复杂,高度波动的环境中执行任务,该环境可以形成具有不同结构的化学模式。这种系统中的电动机可以主动地组装成动态簇和其他独特的非平衡状态。它显示了如何使用具有小特征尺寸的化学图案来抑制电动机的旋转布朗运动,并引导它们沿着规定的路径运动,这些特性可以在应用中加以利用。在具有较大图案长度比例的系统中,区域可以通过趋化效应充当电动机的集水盆。在这样的约束域中产生的集体运动动力学可用于探索活性粒子集体动力学的新方面或促进特定类型的主动自组装。更一般而言,当化学自走式电动机在远离平衡的活性化学介质中运行时,可能出现的各种现象及其潜在应用范围将大大增加。

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