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The Anionic Surfactant/Ionic Liquids Intercalated Reduced Graphene Oxide for High-performance Supercapacitors

机译:用于高性能超级电容器的阴离子表面活性剂/离子液体插层还原氧化石墨烯

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摘要

The thermally reduced graphene oxide (TRG) composites with various interlayer distances were synthesized. These TRG sheets are intercalated with anionic surfactant sodium dodecyl sulfate (SDS) to prevent the restacking between TRG sheets. A facile approach is employed to enlarge the interlayer distance between the TRG sheets by the Coulomb force interaction between the intercalated surfactants and the ionic liquids. A systematic investigation of the morphology and the electrical performances of these EDLC cells was carried out. It was found that the energy density of the cells is improved from 34.9 to 61.8 Wh/kg at 1 A/g suggesting that the increased interlayer distance could enlarge the accessible surface area for the ionic liquid electrolyte.
机译:合成了具有不同层间距离的热还原氧化石墨烯(TRG)复合材料。这些TRG板插入了阴离子表面活性剂十二烷基硫酸钠(SDS),以防止TRG板之间重新堆叠。通过插入的表面活性剂和离子液体之间的库仑力相互作用,采用一种简便的方法来扩大TRG片之间的层间距离。对这些EDLC电池的形态和电性能进行了系统的研究。发现在1 A / g时,电池的能量密度从34.9 Wh / kg改善到34.9 Wh / kg,这表明增加的层间距离可以扩大离子液体电解质的可及表面积。

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