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Importance of liquid fragility for energy applications of ionic liquids

机译:液体脆性对于离子液体能量应用的重要性

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摘要

Ionic liquids (ILs) are salts that are liquid close to room temperature. Their possible applications are numerous, e.g., as solvents for green chemistry, in various electrochemical devices, and even for such “exotic” purposes as spinning-liquid mirrors for lunar telescopes. Here we concentrate on their use for new advancements in energy-storage and -conversion devices: Batteries, supercapacitors or fuel cells using ILs as electrolytes could be important building blocks for the sustainable energy supply of tomorrow. Interestingly, ILs show glassy freezing and the universal, but until now only poorly understood dynamic properties of glassy matter, dominate many of their physical properties. We show that the conductivity of ILs, an essential figure of merit for any electrochemical application, depends in a systematic way not only on their glass temperature but also on the so-called fragility, characterizing the non-canonical super-Arrhenius temperature dependence of their ionic mobility.
机译:离子液体(ILs)是接近室温的液态盐。它们可能的应用是多种多样的,例如,作为绿色化学的溶剂,在各种电化学设备中,甚至用于“外来”目的,例如月球望远镜的旋转液体反射镜。在这里,我们将重点介绍其在储能和转换设备方面的新进展:将ILs作为电解质的电池,超级电容器或燃料电池可能是未来可持续能源供应的重要组成部分。有趣的是,离子液体显示出玻璃态冻结和通用性,但是直到现在,人们对玻璃态物质的动态特性仍知之甚少,主导了它们的许多物理特性。我们表明,ILs的电导率是任何电化学应用的重要指标,它不仅系统地取决于其玻璃温度,而且还取决于所谓的脆性,表征了其非规范的超阿雷尼乌斯温度依赖性离子迁移率。

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