Photofabrication of Highly Transparent Platinum Counter Electrodes at Ambient Temperature for Bifacial Dye Sensitized Solar Cells

摘要

Platinum (Pt) counter electrodes (CEs) have consistently shown excellent electrocatalytic performance and holds the record of the highest power conversion efficiency (PCE) for dye-sensitized solar cells (DSSCs). However, its use for large-scale production is limited either by high temperature required for thermal decomposition of its precursor or by wastage of the material leading to high cost or sophisticated equipment. Here, we report a novel photofabrication technique to fabricate highly transparent platinum counter electrodes by ultraviolet (UV) irradiation of platinic acid (H2PtCl6.6H2O) on rigid fluorine-doped tin oxide (FTO) and flexible indium-doped tin oxide (ITO) on polyethylene terephthalate (PET) substrates. The photofabrication technique is a facile and versatile method for the fabrication of Pt CEs for dye sensitized solar cells (DSSCs). The photofabricated Pt CEs were used to fabricate bifacial DSSCs with power conversion efficiencies (PCEs) attaining 7.29% for front illumination and 5.85% for rear illumination. The highest percentage ratio of the rear illumination efficiency to the front illumination efficiency (ηR) of 85.92% was recorded while the least ηR is 77.91%.