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A facile route for 3D aerogels from nanostructured 1D and 2D materials

机译:纳米结构的1D和2D材料制备3D气凝胶的便捷途径

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摘要

Aerogels have numerous applications due to their high surface area and low densities. However, creating aerogels from a large variety of materials has remained an outstanding challenge. Here, we report a new methodology to enable aerogel production with a wide range of materials. The method is based on the assembly of anisotropic nano-objects (one-dimensional (1D) nanotubes, nanowires, or two-dimensional (2D) nanosheets) into a cross-linking network from their colloidal suspensions at the transition from the semi-dilute to the isotropic concentrated regime. The resultant aerogels have highly porous and ultrafine three-dimensional (3D) networks consisting of 1D (Ag, Si, MnO2, single-walled carbon nanotubes (SWNTs)) and 2D materials (MoS2, graphene, h-BN) with high surface areas, low densities, and high electrical conductivities. This method opens up a facile route for aerogel production with a wide variety of materials and tremendous opportunities for bio-scaffold, energy storage, thermoelectric, catalysis, and hydrogen storage applications.
机译:气凝胶由于其高表面积和低密度而具有许多应用。然而,由多种材料制造气凝胶仍然是一项艰巨的挑战。在这里,我们报告了一种新的方法,可以使用多种材料进行气凝胶生产。该方法基于各向异性的纳米物体(一维(1D)纳米管,纳米线或二维(2D)纳米片)在半稀释过渡时从其胶体悬浮液组装成交联网络的方法。各向同性的集中政权。所得的气凝胶具有高度多孔性和超精细的三维(3D)网络,该网络由1D(Ag,Si,MnO2,单壁碳纳米管(SWNTs))和2D材料(MoS2,石墨烯,h-BN)组成,具有较高的表面积,低密度和高电导率。这种方法为使用多种材料的气凝胶生产开辟了一条便捷的途径,并为生物支架,能量存储,热电,催化和氢存储应用提供了巨大的机会。

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