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Absence of Evidence ≠ Evidence of Absence: Statistical Analysis of Inclusions in Multiferroic Thin Films

机译:缺乏证据≠缺乏证据:多铁性薄膜中夹杂物的统计分析

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摘要

Assertions that a new material may offer particularly advantageous properties should always be subjected to careful critical evaluation, especially when those properties can be affected by the presence of inclusions at trace level. This is particularly important for claims relating to new multiferroic compounds, which can easily be confounded by unobserved second phase magnetic inclusions. We demonstrate an original methodology for the detection, localization and quantification of second phase inclusions in thin Aurivillius type films. Additionally, we develop a dedicated statistical model and demonstrate its application to the analysis of Bi6Ti2.8Fe1.52Mn0.68O18 (B6TFMO) thin films, that makes it possible to put a high, defined confidence level (e.g. 99.5%) to the statement of ‘new single phase multiferroic materials’. While our methodology has been specifically developed for magnetic inclusions, it can easily be adapted to any other material system that can be affected by low level inclusions.
机译:对于一种新材料可能提供特别有利的性能的主张,应始终进行认真的严格评估,尤其是当这些性能可能受到痕量杂质的影响时。对于涉及新的多铁化合物的权利要求而言,这尤其重要,它容易被未观察到的第二相磁性夹杂物所混淆。我们展示了一种检测,定位和定量薄Aurivillius型薄膜中第二相夹杂物的原始方法。此外,我们开发了专用的统计模型,并展示了其在Bi6Ti2.8Fe1.52Mn0.68O18(B6TFMO)薄膜分析中的应用,这使得可以将较高的定义的置信度(例如99.5%)声明为“新型单相多铁性材料”。虽然我们的方法是专门针对磁性夹杂物开发的,但它可以轻松地适应可能受低含量夹杂物影响的任何其他材料系统。

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