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Plasmonic black metals via radiation absorption by two-dimensional arrays of ultra-sharp convex grooves

机译:等离子黑金属通过超锐利凸形凹槽二维阵列的辐射吸收

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摘要

Plasmonic black surfaces formed by two-dimensional arrays of ultra-sharp convex metal grooves, in which the incident radiation is converted into gap surface plasmon polaritons (GSPPs) and subsequently absorbed (via adiabatic nanofocusing), are fabricated and investigated experimentally for gold, nickel, and palladium, using scanning electron microscopy, optical microscopy, and reflection spectroscopy for their characterization. Absolute reflectivity spectra obtained for all fabricated arrays demonstrate very efficient and broadband absorption of unpolarized light exceeding the level of 95%, averaged over the investigated wavelength range of 400–985 nm. The highest averaged absorption level (~97%) is achieved with 250-nm-period arrays in palladium that also has the highest melting temperature (~1552°C), promising thereby potential applications for broadband absorption, e.g., within thermophotovoltaics. For one-dimensional arrays, GSPPs are excited only with the electric field polarized perpendicular to the groove orientation, resulting in 94–96% absorption of the appropriately polarized light for the arrays in nickel and palladium while featuring practically flat surface reflectivity spectra for the orthogonal polarization. The largest ratio (~10.7) between averaged reflectivities for orthogonal polarizations is achieved with the groove arrays in palladium, pointing thereby towards applications as broadband and low-dispersion linear polarizers operating in reflection, e.g., within ultra-fast optics.
机译:由超锐利的凸形金属凹槽的二维阵列形成的等离子黑表面,其中入射辐射被转换为间隙表面等离激元极化子(GSPPs),然后被吸收(通过绝热纳米聚焦),并通过实验研究了金,镍,钯和钯,使用扫描电子显微镜,光学显微镜和反射光谱进行表征。从所有装配好的阵列获得的绝对反射光谱表明,在研究的400-985 nm波长范围内,非偏振光的效率和宽带吸收均超过95%的水平。钯中的250 nm周期阵列具有最高的平均吸收水平(〜97%),该阵列的熔化温度也最高(〜1552°C),从而有望在例如宽带光伏领域获得宽带吸收的潜在应用。对于一维阵列,GSPP仅在垂直于沟槽方向极化的电场中被激发,从而使阵列中的适当偏振光在镍和钯中的吸收率为94–96%,同时具有正交的几乎平坦的表面反射光谱偏振。正交偏振的平均反射率之间的最大比率(〜10.7)是通过钯中的凹槽阵列实现的,因此指向宽带和低色散线性偏振器的应用,例如在超快光学器件中以反射方式工作。

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