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Long-range wetting transparency on top of layered metal-dielectric substrates

机译:分层金属介电基板顶部的远程润湿透明性

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摘要

It has been recently shown that scores of physical and chemical phenomena (including spontaneous emission, scattering and Förster energy transfer) can be controlled by nonlocal dielectric environments provided by metamaterials with hyperbolic dispersion and simpler metal/dielectric structures. At this time, we have researched van der Waals interactions and experimentally studied wetting of several metallic, dielectric and composite multilayered substrates. We have found that the wetting angle of water on top of MgF2 is highly sensitive to the thickness of the MgF2 layer and the nature of the underlying substrate that could be positioned as far as ~100 nm beneath the water/MgF2 interface. We refer to this phenomenon as long range wetting transparency. The latter effect cannot be described in terms of the most basic model of dispersion van der Waals-London forces based on pair-wise summation of dipole-dipole interactions across an interface or a gap separating the two media. We infer that the experimentally observed gradual change of the wetting angle with increase of the thickness of the MgF2 layer can possibly be explained by the distance dependence of the Hamaker function (describing the strength of interaction), which originates from retardation of electromagnetic waves at the distances comparable to a wavelength.
机译:最近显示,许多物理和化学现象(包括自发发射,散射和Förster能量转移)可以由具有双曲线弥散和更简单的金属/介电结构的超材料提供的非局部介电环境控制。这时,我们研究了范德华相互作用,并通过实验研究了几种金属,介电和复合多层基板的润湿性。我们发现,MgF2顶部的水的润湿角对MgF2层的厚度和位于水/ MgF2界面下方约100nm处的下层基板的性质高度敏感。我们将此现象称为远程润湿透明性。后者的影响不能用基于跨界面或分离两种介质的间隙的偶极-偶极相互作用的成对求和的色散范德华-伦敦力的最基本模型来描述。我们推断,实验观察到的润湿角随MgF2层厚度的增加而逐渐变化,可以用Hamaker函数的距离依赖性(描述相互作用的强度)来解释,这是由于电磁波在MgF2层处的延迟而引起的。与波长相当的距离。

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