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Two-dimensional electronic spectra of the photosynthetic apparatus of green sulfur bacteria

机译:绿色硫细菌光合作用装置的二维电子光谱

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摘要

Advances in time resolved spectroscopy have provided new insight into the energy transmission in natural photosynthetic complexes. Novel theoretical tools and models are being developed in order to explain the experimental results. We provide a model calculation for the two-dimensional electronic spectra of Cholorobaculum tepidum which correctly describes the main features and transfer time scales found in recent experiments. From our calculation one can infer the coupling of the antenna chlorosome with the environment and the coupling between the chlorosome and the Fenna-Matthews-Olson complex. We show that environment assisted transport between the subunits is the required mechanism to reproduce the experimental two-dimensional electronic spectra.
机译:时间分辨光谱学的进步为天然光合复合物中的能量传递提供了新的见识。为了解释实验结果,正在开发新颖的理论工具和模型。我们提供了一个用于温热梭菌的二维电子光谱的模型计算,该模型正确描述了最近实验中发现的主要特征和转移时间尺度。根据我们的计算,可以推断出天线中的绿体与环境的耦合以及绿体与Fenna-Matthews-Olson络合物之间的耦合。我们表明,环境辅助的亚基之间的运输是再现实验二维电子光谱所必需的机制。

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