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Influence of chemical disorder on energy dissipation and defect evolution in concentrated solid solution alloys

机译:化学无序对浓固溶体合金能量耗散和缺陷演变的影响

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摘要

A grand challenge in materials research is to understand complex electronic correlation and non-equilibrium atomic interactions, and how such intrinsic properties and dynamic processes affect energy transfer and defect evolution in irradiated materials. Here we report that chemical disorder, with an increasing number of principal elements and/or altered concentrations of specific elements, in single-phase concentrated solid solution alloys can lead to substantial reduction in electron mean free path and orders of magnitude decrease in electrical and thermal conductivity. The subsequently slow energy dissipation affects defect dynamics at the early stages, and consequentially may result in less deleterious defects. Suppressed damage accumulation with increasing chemical disorder from pure nickel to binary and to more complex quaternary solid solutions is observed. Understanding and controlling energy dissipation and defect dynamics by altering alloy complexity may pave the way for new design principles of radiation-tolerant structural alloys for energy applications.
机译:材料研究中的一大挑战是了解复杂的电子相关性和非平衡原子相互作用,以及这种内在特性和动态过程如何影响被辐照材料中的能量转移和缺陷演化。在此我们报告,随着单质集中固溶合金中主要元素数量的增加和/或特定元素浓度的改变,化学无序现象可导致电子平均自由程显着减少,电和热的数量级降低电导率。随后缓慢的能量耗散会在早期阶段影响缺陷动态,因此可以减少有害的缺陷。从纯镍到二元和更复杂的四元固溶体,随着化学无序性的增加,抑制的损伤积累得到了观察。通过改变合金的复杂性来理解和控制能量耗散和缺陷动力学可以为能量应用中耐辐射结构合金的新设计原理铺平道路。

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