(Dimethyl­formamide)(2-methyl­propen­oato)tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine­manganese(II) perchlorate dimethyl­formamide solvate

摘要

In the title complex, [Mn(C4H5O2)(C27H27N7)(C3H7NO)]ClO4·C3H7NO, the Mn^II ion is seven-coordinated in a distorted monocapped trigonal-prismatic geometry formed by a tetra­dentate tris­(1-methyl-1H-benzimidazol-2-ylmeth­yl)amine mol­ecule, a bidentate 2-methacrylate anion and a dimethyl­formamide mol­ecule. The methyl groups of the coordinated dimethyl­formamide mol­ecule and the perchlorate anions are disordered over two positions with occupancy factors of 0.640 (8) and 0.360 (8).