AC Electroluminescent Processes in Pr3+-Activated (Ba0.4Ca0.6)TiO3 Diphase Polycrystals

摘要

We investigated the properties of alternating current (AC)-driven electroluminescence from (Ba0.4Ca0.6)TiO3:Pr³⁺ diphase polycrystal-based device. The results of crystal phases and micrographs, and the symmetrical dual emissions in one AC cycle, indicate the spontaneous formation of a dielectric/phosphor/dielectric sandwich microstructure in (Ba0.4Ca0.6)TiO3:Pr³⁺. The electroluminescent device emits a red light of 617 nm, which is attributed to the ¹D2-³H4 transition of Pr³⁺ in the phosphor phase. At a fixed AC frequency, the intensity of electroluminescence exhibits a steep enhancement when applying an increased driving electric field that is beyond a threshold. In a fixed driving electric field, the intensity of electroluminescence shows a rapid rise at low frequencies, but reaches saturation at high frequencies. Based on a double-injection model, we discussed systematically the electroluminescent processes in a whole cycle of AC electric field, which matched well with the experimental data. Our investigation is expected to expand our understanding of such a diphase electroluminescent device, thereby promoting their applications in lighting and displays.