Bis(μ-35-dimethyl-4H-124-triazol-4-amine-κ2 N 1:N 2)bis­bis­(thio­cyanato-κN)zinc–bis­(35-dimethyl-4H-124-triazol-4-amine-κN 1)bis­(thio­cyanato-κN)zinc (1/2)

摘要

In the crystal structure of the title 1:2 adduct, [Zn2(NCS)4(C4H8N4)2]·2[Zn(NCS)2(C4H8N4)2] or (Ia)·2(Ib), each Zn^II atom is coordinated in a distorted tetra­hedral geometry by four N atoms from two triazole rings of two 4-amino-3,5-dimethyl-1,2,4-triazole (admt) ligands and two NCS⁻ ligands. In (Ia), double N ¹:N ²-bridging admt ligands connect two Zn^II atoms, forming a dimer with a Zn2(admt)2 six-membered metallacycle located on a crystallographic inversion center. In (Ib), the admt ligands exhibit monodentate N ¹-coordination modes. Weak N—H⋯N, N—H⋯S and C—H⋯S hydrogen bonds play an important role in the inter­molecular packing. The S and C atoms of two thiocyanato ligands are disordered over two sets of sites in ratios of 0.57 (3):0.43 (3) and 0.63 (3):0.37 (3), respectively.