(3-Benzoyl-177-trimethyl­bicyclo­2.2.1heptan-2-olato-κ2 OO)bis­2-(2-pyrid­yl)phenyl-κ2 C 1Niridium(III)

摘要

The title compound, [Ir(C11H8N)2(C17H19O2)], has an octa­hedral coordination geometry around the Ir^III atom, retaining the cis-C,C,trans–N,N chelate disposition of the two 2-phenyl­pyridine ligands. The chelate rings are nearly mutually perpendicular [the inter­planar angles range from 85.48 (17) to 89.17 (19)°]. The two 2-(2-pyrid­yl)phenyl ligands are approximately planar, with the plane of the phenyl ring being inclined to that of the pyridine ring by 2.3 (3) and 5.1 (3)° in the two ligands. The inter­planar angle between the phenyl ring in 3-benzoyl-camphor and the IrO2C3 chelate ring is 35.5 (2)°.