Tetra­ethyl­ammonium hexa­cyanidoferrate(III) bis­(diaqua­{66′-dimeth­oxy-22′-o-phenyl­enebis(nitrilo­methyl­idyne)diphenolato}manganese(III))–methanol–ethanol (1/2/2)

摘要

In the title compound, (C8H20N)[Mn(C22H18N2O4)(H2O)2][Fe(CN)6]·2CH3OH·2C2H5OH or [NEt4][Mn(3-Meosalophen)(H2O)2]2[Fe(CN)₆]·2CH₃OH·2C₂H₅OH, the asymmetric unit consists of one half of an [NEt₄]⁺ cation disordered around a twofold axis, the [Mn(3-Meosalophen)(H₂O)₂]⁺ coordination cation, one half of a C ₂ symmetric [Fe(CN)₆]³⁻ anion and disordered methanol and ethanol solvent mol­ecules that are equally populated at two different sites. The Mn^III atom chelated by the 3-Meosalophen ligand adopts a slightly distorted MnN₂O₄ octa­hedral geometry with the coordination completed by two water mol­ecules. The [Mn(3-Meosalophen)(H₂O)₂]⁺ cations, [Fe(CN)₆]^3- anions and solvent mol­ecules are connected into a zigzag chain through hydrogen-bonding inter­actions.