The one-dimensional organic inorganic hybrid compound poly(diethyl­ene­triamine)tetra-μ-iodido-dilead(II)

摘要

A new organic–inorganic hybrid, [Pb2I4(C4H13N3)]n, was obtained by the reaction of C4N3H10 and PbI2 at room temperature. The structure is a three-dimensional polymer resulting from the association of PbI6 octa­hedra and a mixed lead organic–inorganic PbI4(C4N3H13) coordination polyhedron. Both Pb atoms, two I atoms and one N atom lie on a mirror plane. N—H⋯I hydrogen bonds further connect the organic unit and some I atoms.