(R p)-1-{(R)-(Dimethyl­amino)2-(diphenyl­phosphan­yl)phen­ylmethyl}-2-(diphenyl­phosphan­yl)ferrocene chloro­form solvate

摘要

The absolute configuration of the title mol­ecule, [Fe(C5H5)(C38H34NP2)]·CHCl3, is R,R p. The mol­ecular structure is similar to the structure of the solvent-free compound [Fukuzawa, Yamamoto & Kikuchi (2007). J. Org. Chem. >72, 1514–1517], but some torsion angles about the P—Cphen­yl bonds differ by up to 25°. The P atoms and the N atom have a distorted trigonal-pyramidal geometry. The chloro­form solvate group donates a C—H⋯π bond to the central benzene ring and is also involved in six inter­molecular C—H⋯Cl contacts with H⋯Cl distances between 2.96 and 3.13 Å.