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Microfluidic reactors for visible-light photocatalytic water purification assisted with thermolysis

机译:用于热解的可见光光催化水净化的微流体反应器

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摘要

Photocatalytic water purification using visible light is under intense research in the hope to use sunlight efficiently, but the conventional bulk reactors are slow and complicated. This paper presents an integrated microfluidic planar reactor for visible-light photocatalysis with the merits of fine flow control, short reaction time, small sample volume, and long photocatalyst durability. One additional feature is that it enables one to use both the light and the heat energy of the light source simultaneously. The reactor consists of a BiVO4-coated glass as the substrate, a blank glass slide as the cover, and a UV-curable adhesive layer as the spacer and sealant. A blue light emitting diode panel (footprint 10 mm × 10 mm) is mounted on the microreactor to provide uniform irradiation over the whole reactor chamber, ensuring optimal utilization of the photons and easy adjustments of the light intensity and the reaction temperature. This microreactor may provide a versatile platform for studying the photocatalysis under combined conditions such as different temperatures, different light intensities, and different flow rates. Moreover, the microreactor demonstrates significant photodegradation with a reaction time of about 10 s, much shorter than typically a few hours using the bulk reactors, showing its potential as a rapid kit for characterization of photocatalyst performance.
机译:为了有效地利用太阳光,使用可见光的光催化水净化正在深入研究中,但是常规的本体反应器是缓慢且复杂的。本文提出了一种用于可见光光催化的集成式微流体平面反应器,该反应器具有流量控制精细,反应时间短,样品量小和光催化剂耐久性强的优点。另一个特点是,它可以使人们同时使用光源的光能和热能。该反应器由BiVO4涂层玻璃作为基材,空白玻璃载片作为覆盖层以及可紫外线固化的粘合剂层作为垫片和密封剂组成。在微型反应器上安装了蓝色发光二极管面板(占地面积为10 mm×10 mm),以在整个反应器腔室内提供均匀的照射,从而确保了光子的最佳利用,并易于调节光强度和反应温度。该微反应器可以提供用于研究在诸如不同温度,不同光强度和不同流速的组合条件下的光催化作用的通用平台。此外,微反应器显示出显着的光降解作用,反应时间约为10 s,比使用本体反应器的典型反应时间要短得多,显示出其作为表征光催化剂性能的快速试剂盒的潜力。

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