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Data set on stability comparison of emulsions stabilized by cationic fluorosurfactant against conventional surfactants and high thermal performance of fluoropolymer foams

机译:用阳离子含氟表面活性剂稳定的乳液与常规表面活性剂的稳定性比较和含氟聚合物泡沫的高热性能的数据集

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摘要

This data article includes emulsion stability comparison of cationic fluorosurfactant (CFS) against conventional surfactants. Span 80, Hypermer, Tween 80 and CTAB were used as conventional emulsifiers and only after 30 minutes bilayer phase separation observed in emulsions prepared by Tween 80 while CTAB failed to give fluoroemulsion, as compared to the CFS stabilized fluoro-HIPE which demonstrated superb stabilization of more than 72 h without phase separation. Thermal stability of Poly(hexafluorobutyl acrylate)-Divinyl benzene (PHFBA-DVB) was compared with porous polymer prepared by the same concentration of CFS 9 wt% by using trifluoroethyl methacrylate (TFEMA) as monomer phase. Results of PFP prepared with HFBA showed remarkable stability performance at more than 340.69 °C while porous polymer synthesized by TFEMA started to decompose even at 237.36 °C. The main findings based on the data presented here are reported in the paper “A cationicfluorosurfactant for fabrication of high-performance fluoropolymer foams with controllable morphology” (Azhar et al., 2017) .
机译:该数据文章包括阳离子含氟表面活性剂(CFS)与常规表面活性剂的乳液稳定性比较。 Span 80,Hypermer,Tween 80和CTAB用作常规乳化剂,仅在Tween 80制备的乳液中观察到双层相分离30分钟后,而CTAB未能提供氟乳液,而CFS稳定的氟HIPE却表现出优异的稳定性。超过72小时无相分离将聚(六氟丙烯酸丁酯)-二乙烯基苯(PHFBA-DVB)的热稳定性与以相同浓度的CFS 9 wt%使用甲基丙烯酸三氟乙酯(TFEMA)作为单体相制备的多孔聚合物进行了比较。用HFBA制备的PFP在340.69°C以上的温度下表现出了显着的稳定性,而TFEMA合成的多孔聚合物甚至在237.36°C下也开始分解。基于本文提供的数据的主要发现在论文“用于制造形态可控的高性能含氟聚合物泡沫的阳离子含氟表面活性剂”中进行了报道(Azhar等人,2017)。

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