首页> 美国卫生研究院文献>Acta Crystallographica Section E: Crystallographic Communications >μ-11′-Bis(diphenyl­phosphino)ferrocenebis­{(Z)-O-ethyl N-phenyl­thio­carbamato-κSgold(I)} dichloro­methane solvate
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μ-11′-Bis(diphenyl­phosphino)ferrocenebis­{(Z)-O-ethyl N-phenyl­thio­carbamato-κSgold(I)} dichloro­methane solvate

机译:μ-11-双(二苯基­膦基)二茂铁双­ {((Z)-O-乙基N-苯基­硫­氨基甲酸酯-κS金(I)}二氯­甲烷溶剂化物

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摘要

The binuclear title compound, [Au2Fe(C9H10NOS)2(C17H14P)2]·CH2Cl2, which has the Fe atom located on a crystallographic centre of inversion, crystallizes as a 1:1 dichloro­methane solvate, which is disordered about a centre of inversion. There is a small deviation from linearity defined by the SP donor set [S1—Au—P1 angle is 175.35 (5) °] which is due to an intra­molecular Au⋯O contact [3.080 (5) Å]. The primary inter­molecular contacts between binuclear mol­ecules are of the type C—H⋯π, and are arranged so as to form columns in the a-axis direction in which the disordered solvent mol­ecules reside.
机译:双核标题化合物[Au2Fe(C9H10NOS)2(C17H14P)2]·CH2Cl2的Fe原子位于反型晶体学中心,其结晶为1:1的二氯甲烷溶剂化物,该溶剂合物对反型中心无序。与SP供体集[S1-Au-P1角为175.35(5)°]所定义的线性度存在微小偏差,这是由于分子内Au⋯O接触[3.080(5)Å]引起的。双核分子之间的主要分子间接触为CH-π型,并且排列成在无序溶剂分子所处的a轴方向上形成圆柱。

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