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Electrochemical Impedance Spectroscopy as a Tool for Electrochemical Rate Constant Estimation

机译:电化学阻抗谱作为电化学速率常数估算的工具

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摘要

Electrochemical impedance spectroscopy (EIS) was used for advanced characterization of organic electroactive compounds along with cyclic voltammetry (CV). In the case of fast reversible electrochemical processes, current is predominantly affected by the rate of diffusion, which is the slowest and limiting stage. EIS is a powerful technique that allows separate analysis of stages of charge transfer that have different AC frequency response. The capability of the method was used to extract the value of charge transfer resistance, which characterizes the rate of charge exchange on the electrode-solution interface. The application of this technique is broad, from biochemistry up to organic electronics. In this work, we are presenting the method of analysis of organic compounds for optoelectronic applications.
机译:电化学阻抗谱(EIS)与循环伏安法(CV)一起用于有机电活性化合物的高级表征。在快速可逆的电化学过程中,电流主要受扩散速率的影响,扩散速率是最慢且极限的阶段。 EIS是一项强大的技术,可以对具有不同交流频率响应的电荷转移阶段进行单独分析。该方法的功能被用来提取电荷转移电阻的值,该值表征了电极-溶液界面上电荷交换的速率。从生物化学到有机电子学,该技术的应用广泛。在这项工作中,我们介绍了用于光电应用的有机化合物的分析方法。

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